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41.
42.
A newly discovered, extensive sphalerite-bearing breccia (~7.5 wt.% Zn) is hosted in dolomitised Carboniferous limestones overlying Ordovician–Silurian metasedimentary rocks on the Isle of Man. Although base metal sulphide deposits have been mined historically on the island, they are nearly all quartz vein deposits in the metamorphic basement. This study investigates the origin of the unusual sphalerite breccia and its relationship to basement-hosted deposits, through a combination of petrographic, cathodoluminescence, fluid inclusion, stable isotope and hydrogeologic modelling techniques. Breccia mineralisation comprises four stages, marked by episodes of structural deformation and abrupt changes in fluid temperature and chemistry. In stage I, high-temperature (T h > 300°C), high-salinity (20–45 wt.% equiv. NaCl) fluid of likely basement origin deposited a discontinuous quartz vein. This vein was subsequently dismembered during a major brecciation event. Stages II–IV are dominated by open-space filling sphalerite, quartz and dolomite, respectively. Fluid inclusions in these minerals record temperatures of ~105–180°C and salinities of ~15–20 wt.% equiv. NaCl. The δ34S values of sphalerite (6.5–6.9‰ Vienna-Canyon Diablo troilite) are nearly identical to those of ore sulphides from mines in the Lower Palaeozoic metamorphic rocks. The δ18O values for quartz and dolomite indicate two main fluid sources in the breccia’s hydrothermal system, local Carboniferous-hosted brines (~0.5–6.0‰ Vienna standard mean ocean water) and basement-involved fluids (~5.5–11.5‰). Ore sulphide deposition in the breccia is compatible with the introduction and cooling of a hot, basement-derived fluid that interacted with local sedimentary brines.  相似文献   
43.
Isotopic and chemical composition of groundwater from wells and springs, and surface water from the basalt-dominated Axum area (northern Ethiopia) provides evidence for the origin of water and dissolved species. Shallow (depth < 40 m) and deep groundwater are distinguished by both chemical and isotopic composition. Deep groundwater is significantly enriched in dissolved inorganic carbon up to 40 mmol l−1 and in concentrations of Ca2+, Mg2+, Na+ and Si(OH)4 compared to the shallow type.The δ2H and δ18O values of all solutions clearly indicate meteoric origin. Shifts from the local meteoric water line are attributed to evaporation of surface and spring water, and to strong water–rock interaction. The δ13CDIC values of shallow groundwater between −12 and −7‰ (VPDB) display the uptake of CO2 from local soil horizons, whereas δ13CDIC of deep groundwater ranges from −5 to +1‰. Considering open system conditions with respect to gaseous CO2, δ13CDIC = +1‰ of the deep groundwater with highest PCO2 = 10−0.9 atm yields δ13CCO2(gas) ≈ −5‰, which is close to the stable carbon isotopic composition of magmatic CO2. Accordingly, stable carbon isotope ratios within the above range are referred to individual proportions of CO2 from soil and magmatic origin. The uptake of magmatic CO2 results in elevated cations and Si(OH)4 concentrations. Weathering of local basalts is documented by 87Sr/86Sr ratios of the groundwater from 0.7038 to 0.7059. Highest values indicate Sr release from the basement rocks. Besides weathering of silicates, neoformation of solids has to be considered, which results in the formation of, e.g., kaolinite and montmorillonite. In several solutions supersaturation with respect to calcite is reached by outgassing of CO2 from the solution leading to secondary calcite formation.  相似文献   
44.
Paste backfill used to provide ground support in underground mining is generated from full-stream tailings and is almost always placed underground with cement. For the backfill, both the rate of strength development and the final strength are important considerations for design, particularly when the backfill is subsequently exposed in the stope-mining sequence. There is strong evidence that strengths measured on specimens obtained from coring the in situ cemented backfill are much greater than laboratory-cured specimens with the same cement content. The paper reviews some of the experimental evidence showing that one of the major reasons for the different strength is the difference in effective stress acting on the backfill during curing. Laboratory specimens are (almost) always cured under zero total stress, so no effective stress develops. In contrast, backfill in a stope may cure under high effective stress, which develops due to either “conventional” consolidation in free-draining backfills, or to the so-called “self-desiccation” mechanism in fine-grained fills. Evidence is presented showing how the final strength is affected by applying stress to specimens at different stages of curing and at different rates. It is shown that a fully-coupled analysis of the filling behaviour is required to determine the appropriate effective stress regime to apply in curing laboratory specimens, where “fully-coupled” in this context means taking account of the interaction of consolidation/drainage rate, filling rate and cement hydration rate. Curing protocols for laboratory specimens are proposed, which would ensure that the strengths obtained are representative of in situ conditions.  相似文献   
45.
We undertake detailed near-field numerical modelling of the tsunami generated by the 15 July 2009 earthquake (Mw 7.8) in Fiordland, New Zealand. High resolution bathymetry and topography data at Breaksea and Dusky Sounds, and Chalky and Preservation Inlets are derived mostly from digitised New Zealand nautical charts, Shuttle Radar Topographic Mission (SRTM) 3 arc-second data, and General Bathymetric Chart of the Ocean (GEBCO) 30 s data. A combination of continuous and campaign Global Positioning System (GPS), satellite radar (ALOS/PALSAR InSAR images) and seismology data are used to constrain the seafloor deformation for the initial tsunami condition. This source model, derived independently of DART observations, provides an excellent fit to observed tsunami elevations recorded by DART buoy 55015. The model results in the near field show maximum tsunami elevations in the range 0.5–2.0 m inside the sounds and inlets with maximum flow speeds of 3.0 m/s. Along the open coast, maximum tsunami elevations reach 2.0 m. The high flow speeds through the inlets may change the inlet stratifications and water mass inside the sounds. Media reports and field reconnaissance data show some tsunami evidence at Cormorant Cove, Duck and Goose Coves, and Passage Point.  相似文献   
46.
47.
In this paper scattering of elastic waves in fluid–solid interfaces is investigated. We use the Indirect Boundary Element Method to study this wave propagation phenomenon in 2D models. Three models are analyzed: a first one with an interface between two half-spaces, one fluid on the top part and the other solid in the bottom; a second model including a fluid half-space above a layered solid; and finally, a third model with a fluid layer bounded by two solid half-spaces. The source, represented by Hankel's function of the second kind, is always applied in the fluid. This indirect formulation can give to the analyst a deep physical insight on the generated diffracted waves because it is closer to the physical reality and can be regarded as a realization of Huygens' principle. In any event, mathematically it is fully equivalent to the classical Somigliana's representation theorem. In order to gauge accuracy we test our method by comparing with an analytical solution known as Discrete Wave Number. A near interface pulse generates scattered waves that can be registered by receivers located in the fluid and it is possible to infer wave velocities of solids. Results are presented in both time and frequency domain, where several aspects related to the different wave types that emerge from this kind of problems are pointed out.  相似文献   
48.
Soil Organic Carbon (SOC) is one of the key soil properties, but the large spatial variation makes continuous mapping a complex task. Imaging spectroscopy has proven to be an useful technique for mapping of soil properties, but the applicability decreases rapidly when fields are partially covered with vegetation. In this paper we show that with only a few percent fractional maize cover the accuracy of a Partial Least Square Regression (PLSR) based SOC prediction model drops dramatically. However, this problem can be solved with the use of spectral unmixing techniques. First, the fractional maize cover is determined with linear spectral unmixing, taking the illumination and observation angles into account. In a next step the influence of maize is filtered out from the spectral signal by a new procedure termed Residual Spectral Unmixing (RSU). The residual soil spectra resulting from this procedure are used for mapping of SOC using PLSR, which could be done with accuracies comparable to studies performed on bare soil surfaces (Root Mean Standard Error of Calibration = 1.34 g/kg and Root Mean Standard Error of Prediction = 1.65 g/kg). With the presented RSU approach it is possible to filter out the influence of maize from the mixed spectra, and the residual soil spectra contain enough information for mapping of the SOC distribution within agricultural fields. This can improve the applicability of airborne imaging spectroscopy for soil studies in temperate climates, since the use of the RSU approach can extend the flight-window which is often constrained by the presence of vegetation.  相似文献   
49.
The method of geometric-astronomical leveling is presented as a suited technique for the validation of GNSS (Global Navigation Satellite System) heights. In geometric-astronomical leveling, the ellipsoidal height differences are obtained by combining conventional spirit leveling and astronomical leveling. Astronomical leveling with recently developed digital zenith camera systems is capable of providing the geometry of equipotential surfaces of the gravity field accurate to a few 0.1 mm per km. This is comparable to the accuracy of spirit leveling. Consequently, geometric-astronomical leveling yields accurate ellipsoidal height differences that may serve as an independent check on GNSS height measurements at local scales. A test was performed in a local geodetic network near Hanover. GPS observations were simultaneously carried out at five stations over a time span of 48 h and processed considering state-of-the-art techniques and sophisticated new approaches to reduce station-dependent errors. The comparison of GPS height differences with those from geometric-astronomical leveling shows a promising agreement of some millimeters. The experiment indicates the currently achievable accuracy level of GPS height measurements and demonstrates the practical applicability of the proposed approach for the validation of GNSS height measurements as well as the evaluation of GNSS height processing strategies.  相似文献   
50.
The intensity and frequency of heavy snowfall events in the Pyrenees were simulated using data from the HIRHAM regional climate model for a control period (1960?C1990) and two greenhouse emission scenarios (SRES B2 and A2) for the end of the twenty-first century (2070?C2100). Comparisons between future and control simulations enabled a quantification of the expected change in the intensity and frequency of these events at elevations of 1,000, 1,500, 2,000 and 2,500?m a.s.l. The projected changes in heavy snowfall depended largely on the elevation and the greenhouse gas emission scenario considered. At 1,000?m a.s.l., a marked decrease in the frequency and intensity of heavy snowfall events was projected with the B2 and A2 scenarios. At 1,500?m a.s.l., a decrease in the frequency and intensity is only expected under the higher greenhouse gas emission scenario (A2). Above 2,000?m a.s.l., no change or heavier snowfalls are expected under both emission scenarios. Large spatial variability in the impacts of climate change on heavy snowfall events was found across the study area.  相似文献   
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